STAUDINGER REACTION BETWEEN BICYCLIC PHOSPHITES AND AZIDES

被引：2
|
作者：
LEI, GQ
XU, HT
XU, XL
机构：
[1] Beijing Pharmaceutical Chemistry Institute, Beijing 102205, P. R.
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1992年 / 66卷 / 1-4期
关键词：
STAUDINGER REACTION; BICYCLIC PHOSPHITE; IMINOPHOSPHATE;
D O I：
10.1080/10426509208038337
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Staudinger reaction of 4-isopropyl bicyclic phosphite 1 with azides 2-5 to N-substituted bicyclic iminophosphates 8-11 is described. Attempts to obtain the corresponding bicyclic iminophosphates from 1 with azides 6 and 7 were unsuccessful. The microanalytical data, i.r., Raman, 31P n. m.r. and mass spectra of these bicyclic iminophosphates are also reported. The results show that the Staudinger reaction of bicyclic phosphites is more difficult than that of acyclic phosphites, bicyclic phosphites react only with azides (R-N3) in which R are strong electron-attracting groups. The mechanism of the reaction is discussed. © 1992, Taylor & Francis Group, LLC. All rights reserved.
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页码：101 / 106
页数：6
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