NITROUS ACID-CATALYZED OXIDATION OF ALCOHOLS BY OXYGEN IN STRONGLY ACIDIC AQUEOUS-SOLUTIONS

被引：7
|
作者：
LEVINA, A
TRUSOV, S
机构：
来源：
JOURNAL OF MOLECULAR CATALYSIS | 1994年 / 88卷 / 02期
关键词：
ALCOHOLS; CARBONYL COMPOUNDS; NITROUS ACID; OXIDATION; STRONG ACIDS;
D O I：
10.1016/0304-5102(93)E0336-F
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Primary and secondary aliphatic alcohols, as well as benzyl alcohol and allyl alcohol are oxidized to the corresponding carbonyl compounds by oxygen at 20-degrees-C in concentrated perchloric, sulfuric and trifluoroacetic acids solutions in the presence of nitrous acid as the catalyst. The conversion level is dependent on the structure of alcohol molecule and reaction conditions. The possible mechanism is proposed.
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页码：L121 / L123
页数：3
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