SYNTHESIS OF SUBSTITUTED POLYMETHYLENE BY RADICAL POLYMERIZATION OF N,N,N',N'-TETRAETHYLMALEAMIDE AS AN ACYCLIC CIS-1,2-DISUBSTITUTED ETHYLENE

被引：0

作者：

MATSUMOTO, A ^{[1
]}

OTSU, T ^{[1
]}

机构：

[1] OSAKA CITY UNIV,FAC ENGN,DEPT APPL CHEM,SUMIYOSHI KU,OSAKA 558,JAPAN

来源：

POLYMER COMMUNICATIONS | 1991年 / 32卷 / 17期

关键词：

RADICAL POLYMERIZATION; TETRAETHYLMALEAMIDE; SUBSTITUTED POLYMETHYLENE; GEOMETRIC ISOMERS; MONOMER REACTIVITY;

D O I：

暂无

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

N,N,N',N'-Tetraethylmaleamide (TEMAm) was prepared from maleic acid and diethylamine with N,N-dicyclohexylcarbodiimide in dichloromethane at 0-degrees-C. It has been revealed that TEMAm polymerizes in the presence of a radical initiator to give a high molecular weight polymer, which is soluble in benzene, chloroform, tetrahydrofuran and methanol. The polymerization reactivity of TEMAm was compared with other maleic and fumaric derivatives. From infra-red and nuclear magnetic resonance spectra, the polymer obtained was found to consist of a substituted polymethylene structure.

引用

页码：530 / 532

页数：3

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