SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF AN UNUSUAL ETA(3)-LIGATED 1,3-DIPHOSPHACYCLOBUTADIENE MOLYBDENUM COMPLEX VIA CYCLODIMERIZATION OF A PHOSPHAALKYNE - CRYSTAL-STRUCTURE OF [MO(ETA(5)-C9H(7))(CO)(2)(P-ETA(3)-((T)BU)CPC((T)BU)PFBF3)]

被引：14

作者：

HITCHCOCK, PB

MAAH, MJ

NIXON, JF

GREEN, M

机构：

[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

[2] UNIV BATH,SCH CHEM,BATH BA2 7AY,AVON,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 466卷 / 1-2期

关键词：

PHOSPHAALKYNE; MOLYBDENUM; BORON; BRIDGING LIGAND; CYCLOBUTADIENE; CRYSTAL STRUCTURE;

D O I：

10.1016/0022-328X(94)88041-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The phosphaalkyne (t)BuCP undergoes cyclodimerization at a molybdenum centre to afford a 1,3-diphosphacyclobutadiene complex in which, unusually, the four-membered ring is eta(3) ligated to the metal.

引用

页码：153 / 158

页数：6

共 15 条

[1] Di- and triphospha-ferrocenes: Crystal and molecular structures of [Fe(eta(5)-C(5)Me(5))(eta(5)-C(3)(t)Bu(3)P(2))] and of the adducts [Fe(eta(5)-C(5)Me(5))(eta(5)-C(2)(t)Bu(2)P(3))Mo(CO)(5)] and [Fe(eta(5)-C(5)Me(5))(eta(5)-C(2)(t)Bu(2)P(3))W(CO)(5)]
Muller, C
Bartsch, R
Fischer, A
Jones, PG
Schmutzler, R
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 512 (1-2) : 141 - 148
[2] Synthesis, characterisation and reactivity of the first heptamethylindenyl-molybdenum complexes: Crystal structures of [Mo(CO)(eta(2)-MeC CMe)(2)(eta(5)-C9Me7)]BF4 and [Mo(CO)(2)(eta(3)-C3H5)(eta(5)-C9Me7)]
Green, M
McGrath, TD
Thomas, RL
Walker, AP
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 532 (1-2) : 61 - 70
[3] 1ST STRUCTURAL EVIDENCE FOR COMPLEXES CONTAINING ARSADIPHOSPHOLYL ANIONS - CRYSTAL-STRUCTURE OF THE IRON(II) COMPLEX [FE(ETA(5)-C5H5)(ETA(5)-C2(T)BU2ASP2)W(CO)5]
ALJUAID, SS
HITCHCOCK, PB
JOHNSON, JA
NIXON, JF
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 480 (1-2) : 45 - 50
[4] HIGH-NUCLEARITY RUTHENIUM CLUSTER COMPOUNDS CONTAINING PHOSPHORUS LIGANDS - SYNTHESIS AND CRYSTAL-STRUCTURE OF [RU6(CO)11(P(T)BU)4], [RU7(CO)14(P(T)BU)4], AND [H3RU9(CO)20(MU(7)-P)(P(T)BU)3]
CHARALAMBOUS, E
HEUER, L
JOHNSON, BFG
LEWIS, J
LI, WS
MCPARTLIN, M
MASSEY, AD
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 468 (1-2) : C9 - C12
[5] NEW FE-MO AND FE-W FULVALENE-BRIDGED HETEROBIMETALLIC COMPLEXES CONTAINING THE FERROCENYL UNIT - CRYSTAL-STRUCTURE OF [(ETA-C5H5)FE(MU-ETA-ETA-C(5)H(4)IND) MO(CO)(2)(ETA-C3H5)] (IND=1-INDENYL)
WAN, S
BEGLEY, MJ
MOUNTFORD, P
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 489 (1-2) : C28 - C31
[6] SYNTHESIS AND PROPERTIES OF 1,3-((ETA(5)-C6H6)MN(CO)(3))(2)-C5H4 AND 1,4-((ETA(5)-C6H6)MN(CO)(3))(2)-C5H4 - MOLECULAR-STRUCTURE OF [(MU-ETA(5)ETA(5)ETA(5)-C17H15)(CH3)MN2W(CO)(9)]
KIM, JA
CHUNG, TM
CHUNG, YK
JUNG, JH
LEE, SW
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 486 (1-2) : 211 - 216
[7] Synthesis and characterization of polyaromatic azine derivatives of (eta(5)-C5H5)Fe(CO)(2) and (eta(5)-C9H7)Fe(CO)(2): X-ray crystal structures of 4-[(eta(5)-cyclopentadienyl)irondicarbonyl]-7-chloroquinoline, 2-[(eta(5)-cyclopentadienyl)irondicarbonyl]-3-chloroquinoxaline, and 2-[(eta(5)-indenyl)irondicarbonyl]-3-chloroquinoxaline
Hunter, AD
Chukwu, R
Santarsiero, BD
Bott, SG
Atwood, JL
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 526 (01) : 1 - 14
[8] SYNTHESIS OF THE COMPLEXES [N(PPH3)2][M(CO)2(ETA-3-C3H5)-(ETA-6-7,9-C2B10H10ME2)](M=MO OR W) - CRYSTAL-STRUCTURE OF [N(PPH3)2][WBR(CO)3(ETA-6-7,9-C2B10H10ME2)]
LI, SH
MULLICA, DF
SAPPENFIELD, EL
STONE, FGA
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 467 (01) : 95 - 102
[9] ACTIVATION OF A C-O BOND BY REACTION OF A TRIS(CYCLOPENTADIENYL)LANTHANIDE COMPLEX WITH AN ALKALI-METAL IN DIMETHOXYETHANE (DME) - CRYSTAL-STRUCTURES OF [ND(ETA-C5H3(SIME(3))(2)-1,3)(2)(MU-OME)(2)LI(DME)] AND [(CE(ETA-C(5)H(3)(T)BU(2)-1,3)(2)(MU-OME))(2)]
GUNKO, YK
HITCHCOCK, PB
LAPPERT, MF
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 499 (1-2) : 213 - 219
[10] Synthesis and characterization of the linear M-Hg-M trimetallic complexes [eta(5)-Bz(5)C(5)(CO)(3)M](2)Hg and [eta(5)-HO2CC5H4(CO)(3)M](2)Hg (M=Cr, Mo, W). The X-ray crystal structure of [eta(5)-Bz(5)C(5)(CO)(3)W](2)Hg
Song, LC
Zhang, LY
Tao, ZF
Hu, QM
Huang, XY
POLYHEDRON, 1997, 16 (03) : 403 - 408

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