CRYSTAL-STRUCTURES OF HIGHLY CONDUCTING IODINE COMPLEXES OF TTM-TTP

被引：97
作者：
MORI, T
INOKUCHI, H
MISAKI, Y
YAMABE, T
MORI, H
TANAKA, S
机构：
[1] KYOTO UNIV, DEPT MOLEC ENGN, UJI, KYOTO 611, JAPAN
[2] INT SUPERCONDUCT TECHNOL CTR, NAGOYA 456, JAPAN
来源：
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN | 1994年 / 67卷 / 03期
关键词：
D O I：
10.1246/bcsj.67.661
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Methylthio substituted bis-fused tetrathiafulvaleile, TTM-TTP (2.5-bis[4,5-bis(methylthio)-1,3-dithiol-2-yl-idene]-1,3,4,6-tetrathiaphentalene) makes three phases of iodine complexes: (TTM-TTP)I3, alpha-(TTM-TTP)2I3. and beta-(TTM-TTP)2]3. The 1:1 complex exhibits high conductivity. 700 S cm-1 at room temperature. and is metallic down to about T(MI) = 160 K. This complex has uniform columns of the donor molecules. In the semiconducting alpha-(TTM-TTP)2I3, one quarter of the donors is incorporated in the anion sheet. and the sides of the other trimeric donors are blocked by the anion sheets. Beta-(TTM-TTP)213 shows metallic conductivity down to T(MI) = 20 K.
引用
收藏
页码：661 / 667
页数：7
相关论文
共 17 条
[1]  
[Anonymous], 1974, INT TABLES XRAY CRYS, VIV
[2]   CRYSTAL-STRUCTURES OF COMPLEXES BETWEEN HEXACYANOBUTADIENE AND TETRAMETHYLTETRATHIAFULVALENE AND TETRAMETHYLTHIOTETRATHIAFULVALENE [J].
KATAYAMA, C ;
HONDA, M ;
KUMAGAI, H ;
TANAKA, J ;
SAITO, G ;
INOKUCHI, H .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1985, 58 (08) :2272-2278
[3]  
KOBAYASHI H, 1994, SYNTHETIC MET, V107, P33
[4]   THERMOELECTRIC-POWER OF A HUBBARD CHAIN WITH ARBITRARY ELECTRON-DENSITY - STRONG-COUPLING LIMIT [J].
KWAK, JF ;
BENI, G .
PHYSICAL REVIEW B, 1976, 13 (02) :652-657
[5]   METHYLTHIO SUBSTITUTED 2,5-BIS(1',3'-DITHIOL-2'-YLIDENE)-1,3,4,6-TETRATHIAPENTALENE - A BIS-FUSED TETRATHIAFULVALENE [J].
MISAKI, Y ;
NISHIKAWA, H ;
KAWAKAMI, K ;
KOYANAGI, S ;
YAMABE, T ;
SHIRO, M .
CHEMISTRY LETTERS, 1992, (12) :2321-2324
[6]  
MISAKI Y, UNPUB
[7]   THE INTERMOLECULAR INTERACTION OF TETRATHIAFULVALENE AND BIS(ETHYLENEDITHIO)-TETRATHIAFULVALENE IN ORGANIC METALS - CALCULATION OF ORBITAL OVERLAPS AND MODELS OF ENERGY-BAND STRUCTURES [J].
MORI, T ;
KOBAYASHI, A ;
SASAKI, Y ;
KOBAYASHI, H ;
SAITO, G ;
INOKUCHI, H .
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1984, 57 (03) :627-633
[8]   STRUCTURE AND CONDUCTING PROPERTIES OF TMET-TTP RADICAL-CATION SALTS [J].
MORI, T ;
INOKUCHI, H ;
MISAKI, Y ;
NISHIKAWA, H ;
YAMABE, T ;
MORI, H ;
TANAKA, S .
CHEMISTRY LETTERS, 1993, (04) :733-736
[9]   STRUCTURE AND PHYSICAL-PROPERTIES OF (TMEO-TTP)2AU(CN)2 [J].
MORI, T ;
INOKUCHI, H ;
MISAKI, Y ;
NISHIKAWA, H ;
YAMABE, T ;
MORI, H ;
TANAKA, S .
CHEMISTRY LETTERS, 1993, (12) :2085-2088
[10]   CRYSTAL-STRUCTURES OF TTM-TTF COMPLEXES [J].
MORI, T ;
WU, P ;
IMAEDA, K ;
ENOKI, T ;
INOKUCHI, H ;
SAITO, G .
SYNTHETIC METALS, 1987, 19 (1-3) :545-550
12