STRUCTURE AND REACTIVITY OF COPPER(II) CARBOXYLATES .1. COPPER(II) DIPICOLINATES

被引：13

作者：

SILEO, EE

QUINTEROSRIVERO, MF

RIVERO, BE

RIGOTTI, G

BLESA, MA

机构：

[1] UNLP,FAC CIENCIAS EXACTAS,DEPT FIS,CRISTALOG LAB,RA-1900 LA PLATA,ARGENTINA

[2] COMIS NACL ENERGIA ATOM,DEPT QUIM REACTORES,RA-1429 BUENOS AIRES,ARGENTINA

来源：

SOLID STATE IONICS | 1994年 / 73卷 / 1-2期

关键词：

COPPER CARBOXYLATES; DEHYDRATION; DIPICOLINATE; STRUCTURE; THERMAL DECOMPOSITION;

D O I：

10.1016/0167-2738(94)90275-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The crystal and molecular structures of a series of salts formed by copper(II) with dipicolinic acid were used to interpret the dehydration behavior. The morphology of single crystals dehydration of Cu (dipic) . 2H2O (monoclinic and triclinic symmetry), Cu(dipic) . 3H2O and Cu(dipic) (H-2dipic).xH2O was shown to be governed by the arrangement of water molecules along specific orientations.

引用

页码：153 / 159

页数：7