COPPER AND NICKEL-COMPLEXES OF THE NEW PHOSPHADITHIAMACROCYCLE 1-PHENYL-1-PHOSPHA-4,7-DITHIACYCLONONANE

被引：24

作者：

SMITH, RJ

POWELL, AK

BARNARD, N

DILWORTH, JR

BLOWER, PJ

机构：

[1] UNIV CANTERBURY,BIOL LAB,CANTERBURY CT2 7NJ,ENGLAND

[2] UNIV ESSEX,DEPT CHEM,COLCHESTER CO4 3SQ,ESSEX,ENGLAND

[3] UNIV E ANGLIA,SCH CHEM SCI,NORWICH NR4 7TJ,NORFOLK,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 01期

关键词：

D O I：

10.1039/c39930000054

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The novel cyclic ligand 1-phenyl-1-phospha-4-7-dithiacyclononane forms highly stable transition metal and d10 metal complexes; the X-ray structure of the tetrahedral copper(I) complex shows the ligand to be capable of both facial tridentate coordination and monodentate coordination, and the nickel(II) complex is easily and reversibly converted electrochemically.to nickel(I) and nickel(III) complexes.

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页码：54 / 56

页数：3

相关论文

共 13 条

[1] HIGH-YIELD ONE-STEP SYNTHESIS OF 1,4,7-TRITHIACYCLONONANE (9S3) [J].

BLOWER, PJ ;

COOPER, SR .

INORGANIC CHEMISTRY, 1987, 26 (12) :2009-2010

[2] MOLYBDENUM, RHENIUM, AND TUNGSTEN COMPLEXES WITH BI-DENTATE AND TRI-DENTATE PHOSPHINOTHIOLATO-LIGANDS - STRUCTURES OF [MO(PHP(CH2CH2S)2)2] AND [MO(NNME2)(PHP(CH2CH2S)2)2] [J].

BLOWER, PJ ;

DILWORTH, JR ;

LEIGH, GJ ;

NEAVES, BD ;

NORMANTON, FB ;

HUTCHINSON, J ;

ZUBIETA, JA .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (12) :2647-2653

[3] THE CHEMISTRY OF 1,4,7-TRIAZACYCLONONANE AND RELATED TRIDENTATE MACROCYCLIC-COMPOUNDS [J].

CHAUDHURI, P ;

WIEGHARDT, K .

PROGRESS IN INORGANIC CHEMISTRY, 1987, 35 :329-436

[4] CROWN THIOETHER CHEMISTRY [J].

COOPER, SR .

ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (04) :141-146

[5]

COOPER SR, 1990, STRUCT BOND, V72, P1

[6] METAL-TEMPLATED SYNTHESIS OF MACROCYCLIC (TRIPHOSPHINE)MOLYBDENUM COMPLEXES [J].

DIEL, BN ;

BRANDT, PF ;

HALTIWANGER, RC ;

HACKNEY, MLJ ;

NORMAN, AD .

INORGANIC CHEMISTRY, 1989, 28 (14) :2811-2816

[7] METAL-ION SIZE SELECTIVITY OF 1-THIA-4,7-DIAZACYCLONONANE (9-ANEN2S), AND OTHER TRIDENTATE MACROCYCLES - A STUDY BY MOLECULAR MECHANICS CALCULATION, STRUCTURE DETERMINATION, AND FORMATION CONSTANT DETERMINATION OF COMPLEXES OF 9-ANEN2S [J].

HANCOCK, RD ;

DOBSON, SM ;

BOEYENS, JCA .

INORGANICA CHIMICA ACTA, 1987, 133 (02) :221-231

[8] TRILIGATING 11-MEMBERED RINGS CONTAINING TERT-PHOSPHINO SITES - SYNTHESIS AND STRUCTURE [J].

KYBA, EP ;

JOHN, AM ;

BROWN, SB ;

HUDSON, CW ;

MCPHAUL, MJ ;

HARDING, A ;

LARSEN, K ;

NIEDZWIECKI, S ;

DAVIS, RE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (01) :139-147

[9] SYNTHESIS, STRUCTURE, AND REACTIVITY OF THE NICKEL(II) COMPLEX OF 7-AZA-1,4-DITHIACYCLONONANE [J].

MCAULEY, A ;

SUBRAMANIAN, S .

INORGANIC CHEMISTRY, 1990, 29 (15) :2830-2837

[10] PREPARATION AND X-RAY CRYSTAL-STRUCTURE OF A SILVER SANDWICH COMPLEX OF AN AZA-THIA MACROCYCLE [J].

PARKER, D ;

CRAIG, AS ;

FERGUSON, G ;

LOUGH, AJ .

POLYHEDRON, 1989, 8 (24) :2951-2952