PHOTOCHEMISTRY OF CYCLODEXTRIN HOST-GUEST COMPLEXES

被引：27

作者：

BORTOLUS, P ^{[1
]}

GRABNER, G ^{[1
]}

KOHLER, G ^{[1
]}

MONTI, S ^{[1
]}

机构：

[1] UNIV VIENNA, INST THEORET CHEM & STRAHLENCHEM, A-1090 VIENNA, AUSTRIA

来源：

COORDINATION CHEMISTRY REVIEWS | 1993年 / 125卷 / 1-2期

关键词：

D O I：

10.1016/0010-8545(93)85023-W

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Cyclodextrins, when used as molecular receptors, can induce significant modifications of the photophysical and photochemical deactivation pathways of aromatic molecules. On the basis of examples, taken from the authors' work, the factors determining the behaviour of a photoexcited guest molecule in a cyclodextrin cavity are discussed with particular attention to the role of cydodextrin as constraint to molecular degrees of freedom and as tool for controlling the evolution of reaction intermediates to final photoproducts.

引用

页码：261 / 268

页数：8

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