OXIDATION OF VIC-DIOLS TO ALPHA-DICARBONYL COMPOUNDS USING THE OXOAMMONIUM SALT DERIVED FROM 4-ACETAMIDO-TEMPO AND P-TOLUENESULFONIC ACID

被引：61

作者：

BANWELL, MG

BRIDGES, VS

DUPUCHE, JR

RICHARDS, SL

WALTER, JM

机构：

[1] School of Chemistry, University of Melbourne, Victoria 3052, Parkville

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 21期

关键词：

D O I：

10.1021/jo00100a040

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Both open-chain and cyclic vicinal-diols are oxidized to the corresponding alpha-dicarbonyl compound by the oxoammonium salt derived from 4-acetamido-TEMPO and p-toluenesulfonic acid. With certain exceptions, yields are as high or higher than those obtained when Swern reagents are used to effect the same conversions.

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页码：6338 / 6343

页数：6

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