THE REACTION OF CPRU(PPH3)2+ WITH TRIMETHYLENESULFIDE - SYNTHESIS AND MOLECULAR AND CRYSTAL-STRUCTURE OF [CPRU(PPH3)2(SC3H6)]CF3SO3

被引：6
|
作者：
PARK, HS
DRAGANJAC, M
SCOTT, SR
CORDES, AW
EGGLETON, G
机构：
[1] ARKANSAS STATE UNIV,DEPT CHEM & BIOCHEM,STATE UNIV,AR 72467
[2] UNIV ARKANSAS,DEPT CHEM & BIOCHEM,FAYETTEVILLE,AR 72701
[3] SE OKLAHOMA STATE UNIV,DEPT PHYS SCI,DURANT,OK 74701
来源：
INORGANICA CHIMICA ACTA | 1994年 / 221卷 / 1-2期
关键词：
CRYSTAL STRUCTURES; RUTHENIUM COMPLEXES; CYCLOPENTADIENYL COMPLEXES; SULFIDE COMPLEXES;
D O I：
10.1016/0020-1693(94)03952-6
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The isolation and characterization of the trimethylenesulfide-coordinated complex, [CpRu(PPh3)2(SC3H6)]CF3SO3, is reported. The structure of [CpRu(PPh3)2(SC3H6)]CF3SO3 was determined by X-ray diffraction techniques: monoclinic space group I2/a, a = 23.864(10), b = 14.233(3), c = 24.385(7) angstrom, beta = 97.10(3)degrees, Z = 8, R = 0.046, R(w) = 0.065. The Ru is attached to two triphenylphosphine ligands, a cyclopentadienyl and the trimethylenesulfide. The Ru-S distance is 2.3459(20) angstrom.
引用
收藏
页码：157 / 160
页数：4
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