SYNTHESIS OF CATIONIC RUTHENIUM THIOBENZALDEHYDE COMPLEXES THROUGH BETA-HYDRIDE ABSTRACTION

被引：33
|
作者：
SCHENK, WA
STUR, T
DOMBROWSKI, E
机构：
[1] Institut für Anorganische Chemie, Universität Würzburg, Am Hubland
来源：
INORGANIC CHEMISTRY | 1992年 / 31卷 / 05期
关键词：
D O I：
10.1021/ic00031a005
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new and very simple access to complexes of thiobenzaldehydes has been found: beta-hydride abstraction from benzyl mercaptide complexes gives the title compounds in good yields. Eta(1)-Co-ordination of the C = S group is established by spectroscopy and by X-ray structure determination. The complexes undergo [2 + 4] cycloaddition with cyclopentadiene.
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页码：723 / &
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