ELECTROCHEMICAL REDUCTION OF NITROGEN-FLUORINE BONDS - RELEVANCE TO THE REACTIVITY OF ELECTROPHILIC FLUORINATING AGENTS

被引：64

作者：

DIFFERDING, E ^{[1
]}

BERSIER, PM ^{[1
]}

机构：

[1] CIBA GEIGY AG,CENT ANALYT LAB,CH-4002 BASEL,SWITZERLAND

来源：

TETRAHEDRON | 1992年 / 48卷 / 09期

关键词：

FLUORINATION; POLAROGRAPHY; VOLTAMMETRY; REDUCTION; ELECTRON TRANSFER;

D O I：

10.1016/S0040-4020(01)88718-4

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The cyclovoltammetric and polarographic behaviour of nitrogen-fluorine bond containing compounds, including representative electrophilic fluorinating agents is described. The reduction potentials are strongly affected by the substituents on the nitrogen atom and by the electrode material. All reductions are irreversible on the investigated time scale. The influence of these results on the reactivity of electrophilic fluorinating agents is discussed.

引用

页码：1595 / 1604

页数：10

共 41 条

[1] OUTER-SPHERE DISSOCIATIVE ELECTRON-TRANSFER TO ORGANIC-MOLECULES - A SOURCE OF RADICALS OR CARBANIONS - DIRECT AND INDIRECT ELECTROCHEMISTRY OF PERFLUOROALKYL BROMIDES AND IODIDES
ANDRIEUX, CP
GELIS, L
MEDEBIELLE, M
PINSON, J
SAVEANT, JM
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (09) : 3509 - 3520
[2] AUER K, 1990, CHIMIA, V44, P120
[3] N-HALOGENO-COMPOUNDS .10. N-FLUOROQUINUCLIDINIUM TRIFLATE
BANKS, RE
SHARIF, I
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1988, 41 (02) : 297 - 300
[4] ELECTROPHILIC FLUORINATION WITH N-FLUOROQUINUCLIDINIUM FLUORIDE
BANKS, RE
DUBOISSON, RA
TSILIOPOULOS, E
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1986, 32 (04) : 461 - 466
[5] BANKS RE, 1964, CHEM IND-LONDON, P1864
[6] N-HALOGENO COMPOUNDS .12. SITE-SPECIFIC FLUORINATION OF CARBANIONS WITH PERFLUORO-N-FLUOROPIPERIDINE
BANKS, RE
MURTAGH, V
TSILIOPOULOS, E
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1991, 52 (03) : 389 - 401
[7] N-HALOGENO COMPOUNDS .11. PERFLUORO-[N-FLUORO-NORMAL-(4-PYRIDYL)-METHANESULPHONAMIDE], A POWERFUL NEW ELECTROPHILIC FLUORINATING AGENT
BANKS, RE
KHAZAEI, A
[J]. JOURNAL OF FLUORINE CHEMISTRY, 1990, 46 (02) : 297 - 305
[8] N-FLUORO-N-ALKYLSULFONAMIDES - USEFUL REAGENTS FOR THE FLUORINATION OF CARBANIONS
BARNETTE, WE
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (02) : 452 - 454
[9] THE MECHANISM OF ELECTROCHEMICAL REDUCTION OF N-HALOAMIDES IN ACETONITRILE - TRAPPING OF INTERMEDIATE AMIDE ANIONS AND FATHER-SON PROTONATION
BERUBE, D
LESSARD, J
[J]. CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1982, 60 (09): : 1127 - 1142
[10] BERUBE D, 1979, THESIS SHERBROOKE QU

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