DISTRIBUTION OF TROPOSPHERIC OZONE AT BRAZZAVILLE, CONGO, DETERMINED FROM OZONESONDE MEASUREMENTS

An analysis of 33 ozonesonde launches in Brazzaville, Congo (4-degrees-S, 15-degrees-E), between June 1990 and May 1991 is presented. The data indicate highest tropospheric amounts between June and early October, coincident with the dry season and with the presence of enhanced widespread biomass burning. The seasonal cycle of ozone derived from the ozonesonde measurements is in good agreement with the climatological seasonal cycle inferred from the use of satellite data and both seasonal cycles peak in September. Averaged throughout the year, the integrated amount of ozone derived from the ozonesondes is 44 Dobson units (DU) and is 39 DU using the satellite data. Within the troposphere the highest partial pressures are generally found at pressure levels near 700 mbar (approximately 3 km). Using simultaneous ozonesonde data from Ascension Island (8-degrees-S, 15-degrees-W), examples are presented illustrating that differences in the troposphere are primarily responsible for the observed spatial gradients of total ozone observed by TOMS. Calculation of correlation coefficients suggests that total ozone measurements may be a better indicator of the amount of ozone in the troposphere than are surface measurements.