O-17 NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY OF ORGANOSULFUR COMPOUNDS .2. O-17 NMR LANTHANIDE-INDUCED SHIFTS (LIS) OF DIASTEREOTOPIC SULFONYL OXYGENS IN SUBSTITUTED 6-MEMBERED-RING SULFONES

被引：8

作者：

POWERS, TA

EVANS, SA

PANDIARAJAN, K

BENNY, JCN

机构：

[1] UNIV N CAROLINA,WILLIAM RAND KENAN JR LABS CHEM,CB 3290,CHAPEL HILL,NC 27599

[2] ANNAMALAI UNIV,DEPT CHEM,ANNAMALAINAGAR 608002,INDIA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1991年 / 56卷 / 19期

关键词：

D O I：

10.1021/jo00019a023

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The O-17 NMR shifts of diastereotopic sulfonyl oxygens within a series of conformationally homogeneous six-membered-ring organosulfur compounds have been determined. Their lanthanide-induced shifts (LIS), resulting from competitive complexation with the europium metal ion (i.e., Eu(fod)3), provide structural insights into the relative binding potential of the attached diastereotopic sulfonyl oxygens.

引用

页码：5589 / 5594

页数：6

共 12 条

[1] O-17 NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY OF ORGANOSULFUR COMPOUNDS .3. O-17 NMR LANTHANIDE-INDUCED SHIFTS (LIS) OF DIASTEREOTOPIC OXYGEN-ATOMS IN TRANS-2-[ALKYL(ARYL)SULFONYL]CYCLOHEXANOLS
POWERS, TA
EVANS, SA
HETEROATOM CHEMISTRY, 1992, 3 (01) : 41 - 50
[2] DIFFERENTIATION OF SULFONYL OXYGENS IN CYCLIC SYSTEMS BY O-17 NMR LANTHANIDE-INDUCED SHIFTS
BARBARELLA, G
BONGINI, A
CERE, V
PAOLUCCI, C
POLLICINO, S
JOURNAL OF ORGANIC CHEMISTRY, 1993, 58 (23): : 6499 - 6502
[3] C-13 AND O-17 NUCLEAR MAGNETIC-RESONANCE STUDIES OF ORGANOSULFUR COMPOUNDS - THE 4-MEMBERED-RING SULFONE EFFECT
BLOCK, E
BAZZI, AA
LAMBERT, JB
WHARRY, SM
ANDERSEN, KK
DITTMER, DC
PATWARDHAN, BH
SMITH, DJH
JOURNAL OF ORGANIC CHEMISTRY, 1980, 45 (23): : 4807 - 4810
[4] O-17 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY OF SULFOXIDES AND SULFONES - ALKYL SUBSTITUENT INDUCED CHEMICAL-SHIFT EFFECT
DYER, JC
HARRIS, DL
EVANS, SA
JOURNAL OF ORGANIC CHEMISTRY, 1982, 47 (19): : 3660 - 3664
[5] O-17 NUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY OF POLYOXOMETALATES .2. HETERONUCLEAR DECOUPLING OF QUADRUPOLAR NUCLEI
BESECKER, CJ
KLEMPERER, WG
MALTBIE, DJ
WRIGHT, DA
INORGANIC CHEMISTRY, 1985, 24 (07) : 1027 - 1032
[6] O-17 NUCLEAR MAGNETIC-RESONANCE STUDIES .7. ANOMERIC EFFECT IN 2-ALKOXYTETRAHYDROPYRANS STUDIED BY C-13 AND O-17 NMR CHEMICAL-SHIFTS
MCKELVEY, RD
KAWADA, Y
SUGAWARA, T
IWAMURA, H
JOURNAL OF ORGANIC CHEMISTRY, 1981, 46 (24): : 4948 - 4952
[7] SOLID-STATE O-17 NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPIC STUDIES OF ZEOLITES AND RELATED SYSTEMS .2.
TIMKEN, HKC
JANES, N
TURNER, GL
LAMBERT, SL
WELSH, LB
OLDFIELD, E
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (23) : 7236 - 7241
[8] LANTHANIDE INDUCED O-17 NMR SHIFTS OF DIASTEREOTOPIC OXYGEN-ATOMS IN 1-THIADECALIN 1,1-DIOXIDE AND RELATED-COMPOUNDS
POWERS, TA
EVANS, SA
TETRAHEDRON LETTERS, 1990, 31 (41) : 5835 - 5838
[9] INVESTIGATIONS UTILIZING THE O-18 ISOTOPE SHIFT IN C-13 NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPY .1. CORRELATION WITH O-17 NMR CHEMICAL-SHIFTS
RISLEY, JM
MAGNETIC RESONANCE IN CHEMISTRY, 1991, 29 (02) : 143 - 147
[10] DETERMINATION OF THE RATE OF CEREBRAL OXYGEN-CONSUMPTION AND REGIONAL CEREBRAL BLOOD-FLOW BY NONINVASIVE O-17 INVIVO NMR-SPECTROSCOPY AND MAGNETIC-RESONANCE-IMAGING .2. DETERMINATION OF CMRO2 FOR THE RAT BY O-17 NMR, AND CMRO2, RCBF AND THE PARTITION-COEFFICIENT FOR THE CAT BY O-17 MRI
FIAT, D
KANG, SH
NEUROLOGICAL RESEARCH, 1993, 15 (01) : 7 - 22

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