ANTI-STOKES LUMINESCENCE OF CURIUM-248(III) BROMIDE

被引：11
作者：
MURRAY, GM
DELCUL, GD
BEGUN, GM
HAIRE, RG
YOUNG, JP
PETERSON, JR
机构：
[1] UNIV TENNESSEE,DEPT CHEM,KNOXVILLE,TN 37996
[2] OAK RIDGE NATL LAB,DIV CHEM,TRANSURANIUM RES LAB,OAK RIDGE,TN 37831
来源：
CHEMICAL PHYSICS LETTERS | 1990年 / 168卷 / 05期
关键词：
D O I：
10.1016/0009-2614(90)85146-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The anti-Stokes luminescence from six excited-state Stark manifolds of CmBr3 was observed at both 300 and 77 K by using dye laser excitation. The applicable mechanism for the production of the anti-Stokes luminescence is discussed and the crystal field splittings of the luminescence manifolds are correlated with the compound's crystal structure. The very low background produced by this method allows the observation of luminescence from excited states normally obscured by matrix scatter and matrix luminescence. © 1990.
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页码：473 / 476
页数：4
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