ON THE MECHANISM OF CD2+ TRANSFER IN METHANOL ACROSS SATURATED ORGANIC MONOLAYERS

被引：5

作者：

ANASTOPOULOS, A

MOUMTZIS, I

机构：

[1] Laboratory of Physical Chemistry, Chemistry Department (333-2), University of Thessaloniki

来源：

ELECTROCHIMICA ACTA | 1990年 / 35卷 / 11-12期

关键词：

D O I：

10.1016/0013-4686(90)87082-D

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The kinetics of a typical ion-transfer reaction (ITR), like the reduction of Cd2+ ions, across surfactant monolayers is studied in methanol by means of dc-polarography. Combining kinetic parameters with adsorption data an elucidation of the mechanism of the inhibited discharge of Cd2+ is attempted. The analysis of the experimental data does not seem to confirm the incorporation of the pre-adsorbed surfactant molecules by the activated complex, at θ{reversed tilde equals} 1, which has been repeatedly shown to occur in aqueous systems. © 1990.

引用

页码：1805 / 1808

页数：4

共 13 条

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[2]

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