Synthesis and characterisation of mesoporous bone char obtained by pyrolysis of animal bones, for environmental application

被引:86
作者
Patel, Sangeeta [1 ]
Han, Jie [2 ]
Qiu, Wei [1 ]
Gao, Wei [1 ]
机构
[1] Univ Auckland, Dept Chem & Mat Engn, 20 Symonds St, Auckland 1010, New Zealand
[2] Univ Illinois, Dept Civil & Environm Engn, Urbana, IL USA
关键词
Cattle bones; Bone char; Pyrolysis; Adsorbent; 17-beta oestradiol;
D O I
10.1016/j.jece.2015.07.031
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this study, bone char was obtained by pyrolysing bovine and bull bones. The physical and chemical properties of the bone char has been investigated in detail using a number of characterisation techniques. The 400-600 degrees C temperature range with two varied residence time (1 and 2 h) was considered for bone char synthesis. The results indicate that the microstructure, pore diameter and the crystal size have greatly been influenced by the increasing temperature and residence time. The sample prepared at 400 degrees C-2 h, a mesoporous carbon has been prepared which can be considered as a novel low cost adsorbent. The bone char has been used for removal of 17-beta oestradiol from water. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2368 / 2377
页数:10
相关论文
共 32 条
[1]   THE EFFECT OF THERMAL-TREATMENT ON SOME CHARACTERISTICS OF ANIMAL CARBON [J].
ABDELFATTAH, WI ;
GHAZY, TM ;
SELIM, MM .
THERMOCHIMICA ACTA, 1981, 51 (2-3) :287-296
[2]  
Bansal R. C., 1988, ACTIVE CARBON
[3]   An Evaluation of Fish Bone Char as an Appropriate Arsenic and Fluoride Removal Technology for Emerging Regions [J].
Brunson, Laura R. ;
Sabatini, David A. .
ENVIRONMENTAL ENGINEERING SCIENCE, 2009, 26 (12) :1777-1784
[4]   Physical and chemical characterisation of crude meat and bone meal combustion residue: "waste or raw material?" [J].
Deydier, E ;
Guilet, R ;
Sarda, S ;
Sharrock, P .
JOURNAL OF HAZARDOUS MATERIALS, 2005, 121 (1-3) :141-148
[5]   Comparative study of differently treated animal bones for Co2+ removal [J].
Dimovic, S. ;
Smiciklas, I. ;
Plecas, I. ;
Antonovic, D. ;
Mitric, M. .
JOURNAL OF HAZARDOUS MATERIALS, 2009, 164 (01) :279-287
[6]  
Fernane F, 2013, INT C ENV SCI TECHN
[7]   Effect of the calcination temperature on the composition and microstructure of hydroxyapatite derived from human and animal bone [J].
Figueiredo, M. ;
Fernando, A. ;
Martins, G. ;
Freitas, J. ;
Judas, F. ;
Figueiredo, H. .
CERAMICS INTERNATIONAL, 2010, 36 (08) :2383-2393
[8]  
Figueiredo MM, 2012, INFRARED SPECTROSCOPY - LIFE AND BIOMEDICAL SCIENCES, P315
[9]   Adsorption kinetics and isotherm of methylene blue and its removal from aqueous solution using bone charcoal [J].
Ghanizadeh, Gh. ;
Asgari, G. .
REACTION KINETICS MECHANISMS AND CATALYSIS, 2011, 102 (01) :127-142
[10]   Chemical and physicochemical characterization of porous hydroxyapatite ceramics made of natural bone [J].
Joschek, S ;
Nies, B ;
Krotz, R ;
Göpferich, A .
BIOMATERIALS, 2000, 21 (16) :1645-1658