Modeling of Phase and Chemical Equilibrium on the Quaternary System Acetic Acid, n-Butanol, Water and n-Butylacetate

被引:4
作者
Mandagaran, Beatriz A. [1 ]
Campanella, Enrique A. [1 ,2 ]
机构
[1] INTEC UNL CONICET, Buenos Aires, DF, Argentina
[2] FICH UNL, Buenos Aires, DF, Argentina
来源
CHEMICAL PRODUCT AND PROCESS MODELING | 2009年 / 4卷 / 01期
关键词
phase equilibrium; chemical equilibrium; esterification; reactive distillation;
D O I
10.2202/1934-2659.1411
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The correlation of the data for phase and chemical equilibrium in acetic acid-n-butanol-water-n-butylacetate is presented. The azeotropic properties, the topological structure and the existence of a reactive azeotrope are discussed. The data are correlated by Hayden-O'Connell second virial coefficients and NRTL. Chemical equilibrium constant has a strong influence on the reactive azeotrope.
引用
收藏
页数:22
相关论文
共 50 条
  • [31] Chemical equilibrium and liquid-liquid equilibrium in ternary mixtures of formaldehyde, water, and isobutanol/ n-butanol between 295 K and 348 K
    Winklbauer, Lukas
    Burger, Jakob
    [J]. FLUID PHASE EQUILIBRIA, 2025, 594
  • [32] Chemical Equilibrium in the System Acetic acid-n-Amyl Alcohol-n-Amyl Acetate-Water at 323.15 K and Atmospheric Pressure: Experimental Data and Equilibrium Constant Estimation
    Misikov, Georgii
    Zolotovsky, Konstantin
    Samarov, Artemiy
    Prikhodko, Igor
    Toikka, Maria
    Toikka, Alexander
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2024, 69 (03) : 1169 - 1177
  • [33] Molybdena-vanadia supported on alumina: Effective catalysts for the esterification reaction of acetic acid with n-butanol
    Mitran, Gheorghita
    Pavel, Octavian-Dumitru
    Marcu, Ioan-Cezar
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2013, 370 : 104 - 110
  • [34] Efficient esterification of n-butanol with acetic acid catalyzed by the Bronsted acidic ionic liquids: influence of acidity
    Lunagariya, Jignesh
    Dhar, Abhishek
    Vekariya, Rohit L.
    [J]. RSC ADVANCES, 2017, 7 (09) : 5412 - 5420
  • [35] Hydrothermal Synthesis of Nanosized Sulfated Zirconia as an Efficient and Reusable Catalyst for Esterification of Acetic Acid with n-Butanol
    Yu, Shengjian
    Jiang, Pingping
    Dong, Yuming
    Zhang, Pingbo
    Zhang, Yue
    Zhang, Weijie
    [J]. BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2012, 33 (02): : 524 - 528
  • [36] Study of the esterification reaction of acetic acid with n-butanol over supported WO3 catalysts
    Mitran, Gheorghita
    Yuzhakova, Tatiana
    Popescu, Ionel
    Marcu, Ioan-Cezar
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2015, 396 : 275 - 281
  • [37] Esterification of butyric acid with n-butanol: Kinetic study using experimental data and modeling
    Pathak, Ashutosh Kumar
    Kundu, Madhusree
    [J]. INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 2024, 56 (04) : 188 - 198
  • [38] Mild acid functionalization of metal-organic framework and its catalytic effect on esterification of acetic acid with n-butanol
    Hu, Xijun
    Ma, Kai
    Sabbaghi, Aghil
    Chen, Xuanming
    Chatterjee, Amrita
    Lam, Frank L. Y.
    [J]. MOLECULAR CATALYSIS, 2020, 482
  • [39] Chemical equilibrium and liquid-phase splitting in acetic acid plus n-propanol plus n-propyl acetate plus water system at 293.15 and 353.15 K
    Samarov, A. A.
    Toikka, M. A.
    Naumkin, P. V.
    Toikka, A. M.
    [J]. THEORETICAL FOUNDATIONS OF CHEMICAL ENGINEERING, 2016, 50 (05) : 739 - 745
  • [40] Effect of Nickel Promoter on Solvent-Free Sulphated Zirconia Catalyst for the Esterification of Acetic Acid with n-Butanol
    Wijayanti, Hesti
    Duangchan, Apinya
    [J]. CANADIAN JOURNAL OF CHEMICAL ENGINEERING, 2016, 94 (01) : 81 - 88