SYNTHESIS AND CHARACTERIZATION OF LOW-VALENT COMPLEXES OF MOLYBDENUM-CONTAINING THE TRIDENTATE LIGAND PHP(CH(2)CH(2)PPH(2))(2) (TRI)

被引：0

作者：

GEORGE, TA

HAMMUND, HH

机构：

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 503卷 / 01期

关键词：

MOLYBDENUM; PHOSPHINE; PHOSPHITE; DINITROGEN; ETA(6)-BENZENE COMPLEX; ETA(6)-ARENE COMPLEX;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reduction of [MoCl3(TRI)] with sodium amalgam in the presence of potential ligands results in the formation of a series of new complexes containing eta(3)-TRI. These include [Mo(eta(6)-C(6)H(5)R)(TRI)] (where R = H, Me, MeO), [Mo(eta(5)C(5)H(5))(H)(TRI)], [Mo(TRI)(P(OR)(3))(3)] (where R = Me, Et), and fac-[Mo(N-2)(TRI)(PMe(3))(2)]. Protonation of the arene complexes results in the formation of both mono- and diprotonated complexes.

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页码：C1 / C3

页数：3

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