THE VOLUME DEPENDENCE OF THE MAGNETIZATION AND NMR OF FE4N AND MN4N

The forced volume magnetostriction and the NMR of ferromagnetic Fe4N and ferrimagnetic Mn4N have been measured in the ordered state. At 4.2 K the magnetization (sigma) per unit mass and the effective field (H(I)) at the nucleus of the Fe(I) site of Fe4N are found to change with pressure such that partial derivative ln sigma/partial derivative P congruent-to partial derivative ln\H(I)\partial derivative P < 0, while for Mn4N partial derivative ln sigma/partial derivative P congruent-to 6 partial derivative ln\H(I)\/partial derivative P > 0. The result for Mn4N is interpreted as showing that the magnitude of the small (negative) moment on the Mn(II) site decreases more rapidly under pressure than does the large Mn(I) moment. The value of partial derivative In\H(I)\/partial derivative P for Mn4N was found to be a strong function of temperature such that partial derivative ln T(N)/partial derivative P congruent-to 5.2 Mbar-1. An analysis of the Mn4N NMR data suggests that the discrepancy between the calculated (spin) and measured moment at the Mn(I) site may be due to a small orbital moment at that site.