POLY-1-BUTENE - ITS PREPARATION, PROPERTIES AND CHALLENGES

被引:270
作者
LUCIANI, L
SEPPALA, J
LOFGREN, B
机构
[1] Neste Oy, Kulloo, Finl, Neste Oy, Kulloo, Finl
关键词
COPOLYMERS - MONOMERS - Production - POLYMERIZATION - Reaction Kinetics - POLYMERS - Physical Properties;
D O I
10.1016/0079-6700(88)90010-X
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
More than 30 years after the synthesis of isotactic poly-1-butene there is still no large commercial production of the resin, nor major applications to compare with those of the lighter olefin polymers polyethylene and polypropylene. The chief reason for the slower commercialization has been the low level of monomer availability and its higher price compared with ethylene and propylene. However, poly-1-butene has several highly attractive properties. It is tough, retains strength at elevated temperatures, is resistant to stress cracking and abrasion, and exhibits good long-term creep resistance and strength even at elevated temperatures. This paper reviews the preparation, properties and challenges of poly-1-butene.
引用
收藏
页码:37 / 62
页数:26
相关论文
共 168 条
[1]  
Armeniades C. D., 2006, J MACROMOL SCI, V1, P309
[2]  
ARONNE A, 1986, EUR POLYM J, V23, P703
[3]  
ASADA T, 1985, POLYM SCI PP, V23, P1369
[4]   THE C-13 NMR CHEMICAL-SHIFT OF POLY(1-BUTENE) REFERRING TO THAT OF 2,4,6,8,10,12,14,16,18-NONAETHYLNONADECANE AND A COMPARISON OF THE CHEMICAL-SHIFTS BETWEEN POLY(1-BUTENE) AND POLYPROPYLENE [J].
ASAKURA, T ;
OMAKI, K ;
ZHU, SN ;
CHUJO, R .
POLYMER JOURNAL, 1984, 16 (09) :717-726
[5]   Granulation, Phase Change, and Microstructure - Kinetics of Phase Change. III [J].
Avrami, M .
JOURNAL OF CHEMICAL PHYSICS, 1941, 9 (02) :177-184
[6]   Kinetics of phase change I - General theory [J].
Avrami, M .
JOURNAL OF CHEMICAL PHYSICS, 1939, 7 (12) :1103-1112
[7]  
Avrami M., 1940, J CHEM PHYS, V8, P212, DOI [DOI 10.1063/1.1750631, 10.1063/1.1750631]
[8]  
BALL M, 1985, HIGH PERFORMANCE PLA
[9]   THE NUMBER OF PROPAGATING SPECIES AND SOME RATE CONSTANTS OF ELEMENTARY ACTS FOR THE POLYMERIZATION OF ETHYLENE AND ALPHA-OLEFINS USING SUPPORTED ZIEGLER CATALYSTS [J].
BAULIN, AA ;
RODIONOV, AG ;
IVANCHEV, SS ;
DOMAREVA, NM .
EUROPEAN POLYMER JOURNAL, 1980, 16 (10) :937-940
[10]  
BOON J, 1979, ZIEGLERNATTA CATALYS