PREPARATION AND ELECTROCHEMICAL RESPONSE OF POLY(4-VINYLPYRIDINE)-COORDINATED OXO-ACETATO TRIRUTHENIUM CLUSTER FILM

被引：17

作者：

AKASHI, D ^{[1
]}

KIDO, H ^{[1
]}

SASAKI, Y ^{[1
]}

ITO, T ^{[1
]}

机构：

[1] TOHOKU UNIV, FAC SCI, DEPT CHEM, SENDAI, MIYAGI 980, JAPAN

来源：

CHEMISTRY LETTERS | 1992年 / 01期

关键词：

D O I：

10.1246/cl.1992.143

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The trinuclear ruthenium cluster [Ru(III)3(mu-3-O)(mu-CH3COO)6-(pyridine)2(CH3OH)]+ was incorporated into poly(4-vinylpyridine) through substitution of the pyridyl residue for CH3OH to form a new macromolecular complex, which showed distinctive reversible cyclic voltammographic waves at -0.05 and +0.95 V vs. SCE in aqueous CF3COO- medium at pH 3, when coated on a glassy carbon electrode as a transparent film.

引用

页码：143 / 146

页数：4

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