DIMETHYLALLENEDIYL AS AN ETA-1,ETA-2-BRIDGING LIGAND IN A DIZIRCONOCENE COMPLEX

被引：23

作者：

BINGER, P

LANGHAUSER, F

GABOR, B

MYNOTT, R

HERRMANN, AT

KRUGER, C

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1992年 / 06期

关键词：

D O I：

10.1039/c39920000505

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Treatment of (eta-2-ethene)(trimethylphosphane)zirconocene 1 with 3,3-dimethylcyclopropene 2 leads to the formation of a new type of bis(ethylzirconocene) complex 3 with 3,3-dimethylallenediyl as a mu-1, mu-2-bridging ligand; the crystal structure of 3 is determined by X-ray analysis.

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页码：505 / 506

页数：2

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