SYNTHESIS OF BETA-HEMATIN BY DEHYDROHALOGENATION OF HEMIN

被引:60
作者
BOHLE, DS
HELMS, JB
机构
[1] Department of Chemistry, University of Wyoming, Laramie
关键词
D O I
10.1006/bbrc.1993.1652
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
β-Hematin, the metalloporphyrin coordination polymer present in malaria pigment, is prepared in high yield by the abstraction of HCl from hemin with a non-coordinating base in strictly anhydrous conditions. The product of this preparation is characterized by elemental analysis, infrared and diffuse reflectance spectroscopies and demonstrated to be identical to prior preparations. © 1993 Academic press, Inc.
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页码:504 / 508
页数:5
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