Kinetic and theoretical studies of the hydration of carbon suboxide

被引：11
作者：
Allen, AD
McAllister, MA
Tidwell, TT
机构：
[1] UNIV TORONTO,DEPT CHEM,TORONTO,ON M5S 1A1,CANADA
[2] UNIV CALIF LOS ANGELES,DEPT CHEM,LOS ANGELES,CA 90024
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 24期
关键词：
D O I：
10.1039/c39950002547
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hydration rates in H2O of carbon suboxide are substantial but less than those of ketene, by factors of 2.5 x 10(3) and 5.2 x 10(4) for the neutral and acid-catalysed reactions, respectively, in qualitative agreement with ab initio calculated stabilities of probable intermediates.
引用
收藏
页码：2547 / 2548
页数：2
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[31]   The catalytic hydrogenation of carbon suboxide [J].
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[34]   On knowledge of carbon suboxide. [J].
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[35]   The spectrum and photochemistry of carbon suboxide [J].
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[36]   REACTION OF CARBON SUBOXIDE WITH DIAZOMETHANE [J].
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[37]   SOUND VELOCITY IN CARBON SUBOXIDE [J].
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