Kinetic and theoretical studies of the hydration of carbon suboxide

被引：11
|
作者：
Allen, AD
McAllister, MA
Tidwell, TT
机构：
[1] UNIV TORONTO,DEPT CHEM,TORONTO,ON M5S 1A1,CANADA
[2] UNIV CALIF LOS ANGELES,DEPT CHEM,LOS ANGELES,CA 90024
来源：
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 24期
关键词：
D O I：
10.1039/c39950002547
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Hydration rates in H2O of carbon suboxide are substantial but less than those of ketene, by factors of 2.5 x 10(3) and 5.2 x 10(4) for the neutral and acid-catalysed reactions, respectively, in qualitative agreement with ab initio calculated stabilities of probable intermediates.
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页码：2547 / 2548
页数：2
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