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SIMULTANEOUS SPECTROPHOTOMETRIC DETERMINATION OF COBALT, COPPER AND NICKEL BY THE FULL SPECTRUM TECHNIQUE IN THE FOURIER DOMAIN
被引:9
|作者:
REN, SX
GAO, L
机构:
[1] Department of Chemistry, Inner Mongolia University, Huhehot, 010021, Inner Mongolia
关键词:
SIMULTANEOUS DETERMINATION OF CO(II);
CU(II) AND NI(II);
FULL SPECTRUM TECHNIQUES;
SPECTROPHOTOMETRY;
D O I:
10.1080/00032719508002773
中图分类号:
O65 [分析化学];
学科分类号:
070302 ;
081704 ;
摘要:
Two methods, the multivariate linear regression and full spectrum technique in the fourier domain, were studied for simultaneous determination of cobalt( II:), copper( II:) and nickel(II) in mixture. Two programs, SPGRMLR and SPGRFSQ, were designed to perform these calculations. In the full spectrum method, seven error functions were calculated for estimating the number of factors and data reduction was fulfilled by factor analysis. Experimental results showed the full spectrum method to be more powerful than multivariate linear regression. Both methods were demonstrated to be successful in the present case.
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页码:1665 / 1679
页数:15
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