ELECTROSYNTHESIS OF CYCLOPROPANE DERIVATIVES BY A PERKIN-TYPE REACTION

被引：5

作者：

PETROSYAN, VA

VASILEV, AA

TATARINOVA, VI

机构：

[1] N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, Moscow, 117913

来源：

RUSSIAN CHEMICAL BULLETIN | 1994年 / 43卷 / 01期

关键词：

CH-ACIDS; 1,2-DIHALOALKANES; CYCLOPROPANES; ELECTROSYNTHESIS; ELECTROREDUCTION; ELECTROGENERATED BASES; AZOBENZENE;

D O I：

10.1007/BF00699141

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrolysis of active methylene compounds at a Pt cathode in MeCN in the presence of vicinal dihaloalkanes leads to cyclopropane derivatives in yields up to 90 %. In the cases of CH-acids with low pK(a) it is expedient to apply more active dihaloalkanes, while for CH-acids with higher pK(a) the desired product yields may be raised using electrogenerated bases.

引用

页码：84 / 88

页数：5

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