NUCLEAR-QUADRUPOLE COUPLING IN D2O

被引：10

作者：

BHATTACHARJEE, R ^{[1
]}

MUENTER, JS ^{[1
]}

MARSHALL, MD ^{[1
]}

机构：

[1] AMHERST COLL,DEPT CHEM,AMHERST,MA 01002

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1991年 / 145卷 / 02期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0022-2852(91)90117-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

Stark-hyperfine transitions have been observed in the l11 and l10 rotational states of D2O to characterize the deuterium quadrupole coupling interaction. The diagonal elements of the eQq tensor, in the principal inertial coordinate system, are eQqaa = 153.92(11)kHz, eQqbb = 22.12(11)kHz, and eQqcc = -175.037(11)kHz. These results provide eQq constants, with a minimum of centrifugal distortion, for the analysis of hyperfine data for water containing van der Waals complexes. © 1991.

引用

页码：302 / 307

页数：6

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