IMPROVED SYNTHESIS OF METHYL 4,6-O-BENZYLIDENE-3-CYANO-2,3-DIDEOXY-ALPHA-D-ERYTHRO-HEX-2-ENOPYRANOSIDE AND METHYL 4,6-O-BENZYLIDENE-2,3-DIDEOXY-3-C-FORMYL-ALPHA-D-ERYTHRO-HEX-2-ENOPYRANOSIDE

被引：10

作者：

SPANEVELLO, RA

PELLEGRINET, SC

机构：

[1] Instituto de Química Orgánica de Síntesis, CONICET, Universidad Nacional de Rosario, Facultad de Ciencias Bioquímicas y Farmacéuticas, 2000, Rosario

来源：

SYNTHETIC COMMUNICATIONS | 1995年 / 25卷 / 22期

关键词：

D O I：

10.1080/00397919508015503

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Simple and efficient route to the title compounds by using diethyl aluminium cyanide in benzene for the epoxide ring opening and the electrophilic assistance of LiClO4 during the isomerization-elimination process.

引用

页码：3663 / 3670

页数：8

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