REACTIONS OF CH2 WITH ADSORBED OXYGEN TO PRODUCE OXYGENATED COMPOUNDS ON RH(111)

被引：32

作者：

SOLYMOSI, F ^{[1
]}

KLIVENYI, G ^{[1
]}

机构：

[1] ATTILA JOZSEF UNIV,INST SOLID STATE & RADIOCHEM,H-6701 SZEGED,HUNGARY

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1995年 / 99卷 / 22期

关键词：

D O I：

10.1021/j100022a003

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reaction pathways of CH2 in the presence of coadsorbed oxygen atoms were investigated by means of temperature-programmed desorption and high-resolution electron energy loss spectroscopy. The CH2 species was produced by the dissociation of CH2I2. Adsorbed oxygen atoms reacted with CH2 above 170 K to give formaldehyde, which desorbed from the surface after its formation. Above 340 K, the oxidation of CH2 led to the production of CO2 and H2O.

引用

页码：8950 / 8953

页数：4

共 50 条

[41] Reactions of ionised methyl pent-4-enyl ether, CH2=CH(CH2)3OCH3•+
Bowen, RD
Mandeville, SJ
Trikoupis, MA
Terlouw, JK
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2001, 210 (1-3) : 447 - 457
[42] Laboratory spectrum of the 111-202 rotational transition of CH2
Michael, EA
Lewen, F
Winnewisser, G
Ozeki, H
Habara, H
Herbst, E
ASTROPHYSICAL JOURNAL, 2003, 596 (02): : 1356 - 1362
[43] Trivinylphosphineborane (CH2=CH)3PBH3 and related compounds
Monkowius, U
Nogai, S
Schmidbaur, H
DALTON TRANSACTIONS, 2003, (05) : 987 - 991
[44] Synthesis and spectroscopic characterization of pyrrolidyl and piperidyl dithioformate derivatives of dimethyltellurium(IV) compounds. Crystal structures of Me2Te[S2CN(CH2)(3)CH2](2), Me2Te[S2CN(CH2)(4)CH2](2), Me2Te{[S2CN(CH2)(3)CH2][S2CN(CH2)(4)CH2]}, Me2TeCl[S2CN(CH2)(3)CH2], Me2TeBr[S2CN(CH2)(3)CH2], Me2TeI[S2CN(CH2)(3)CH2], Me2TeCl[S2CN(CH2)(4)CH2], and Me2TeI[S2CN(CH2)(4)CH2]
Drake, JE
Yang, JC
INORGANIC CHEMISTRY, 1997, 36 (09) : 1890 - 1903
[45] Generation and reactions of CH2 and C2H5 species on Mo2C/Mo(111) surface
Solymosi, F
Bugyi, L
Oszkó, A
Horváth, I
JOURNAL OF CATALYSIS, 1999, 185 (01) : 160 - 169
[46] ACTION OF ORGANOMETALLIC COMPOUNDS, CH2 = CH - CH = CH - CH2 - M AND C6H5CH = CH - CH2 - M (M = LI, ZNBR, AL2-3CL) ON KETONES - STUDY OF REVERSIBILITY OF REACTION
GERARD, F
MIGINIAC, P
BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE PARTIE II-CHIMIE MOLECULAIRE ORGANIQUE ET BIOLOGIQUE, 1974, (11): : 2527 - 2533
[47] Heterogeneity of oxygen-potassium-covered Rh(111): Detection with photoemission of adsorbed noble gases
Janssens, TVW
Castro, GR
Wandelt, K
SURFACE SCIENCE, 1998, 399 (01) : 15 - 28
[48] The effect of adsorbed oxygen on the stability of NCO on Rh(111) studied by reflection absorption infrared spectroscopy
Kiss, J
Solymosi, F
JOURNAL OF CATALYSIS, 1998, 179 (01) : 277 - 282
[49] Photoelectron spectroscopy of low valent organophosphorus compounds, P-CH3, H-P=CH2 and P=CH2
Mukhopadhyay, Deb Pratim
Gerlach, Marius
Hartweg, Sebastian
Fischer, Ingo
Loison, Jean-Christophe
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2022, 24 (18) : 10993 - 10999
[50] REACTIONS OF FORMIC-ACID AND FORMALDEHYDE ON RH(111) AND RH(111)-(2X2)O SURFACES
HOUTMAN, C
BARTEAU, MA
SURFACE SCIENCE, 1991, 248 (1-2) : 57 - 76

← 1 2 3 4 5 →