RHODIUM-CATALYZED CARBONYLATION OF METHYL GLYCOLATE AND GLYCOLIC ACID

被引：2
作者：
LEE, JS
KIM, EJ
LEE, SH
PARK, KH
机构：
[1] Department of Chemical Engineering, Pohang Institute of Science and Technology, Pohang
[2] Lucky R and D Centre, Taejeon
来源：
KOREAN JOURNAL OF CHEMICAL ENGINEERING | 1991年 / 8卷 / 01期
关键词：
D O I：
10.1007/BF02697698
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Catalytic carbonylation of methyl glycolate in the presence of a homogeneous Rh complex and an iodide promoter yields acetoxy methyl acetate and acetic acid. Carbonylation of glycolic acid under the same conditions gives acetic acid and CO2, probably from decomposition of the malonic acid intermediate.
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页码：53 / 55
页数：3
相关论文
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