Solid-phase extraction derivative aromatic compounds in water samples and determination of using GC-FID

被引:0
作者
Moghimi, Ali [1 ]
Ghazal, Asghar [2 ]
机构
[1] East Tehran Ghiamdasht Campus Islamic Azad Univ, Dept Chem, Tehran, Iran
[2] Saveh Campus Islamic Azad Univ, Dept Chem, Saveh, Iran
关键词
Solid phase extraction; Water analyzing; active carbon; derivative aromatic (phenol compounds); Gas chromatography flame ionization detection (GC-FID);
D O I
暂无
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
A simple method to pre-concentrated derivative aromatic compounds on active carbon in column has been applied as stationary phase which is used to measure the concentration of derivative aromatic compounds in water samples by means of solid-phase extraction. To measure 250 cc water samples and 250mg active carbon could be applied. Next step is to measure the derivative aromatic compounds by injecting them to the gas chromatography with flame ionization. The advantages of applying gas chromatography-flame ionization detection (GC-FID) with SPE in presence Carbon active are high sensitivity, High speed transformation of aromatic compounds and improving ration standard for river waters with derivative aromatic compounds in the range of ppb or those with less than 10% of LOD. The quantity of extraction could be affected by sample's pH, amount of solvent, washing liquid type, solvent and flow rates of the sample solutions.
引用
收藏
页码:397 / 403
页数:7
相关论文
共 32 条
[1]   Conductive polymers as new media for solid-phase extraction: Isolation of chlorophenols from water sample [J].
Bagheri, H ;
Saraji, M .
JOURNAL OF CHROMATOGRAPHY A, 2003, 986 (01) :111-119
[2]   New polymeric sorbent for the solid-phase extraction of chlorophenols from water samples followed by gas chromatography-electron-capture detection [J].
Bagheri, H ;
Saraji, M .
JOURNAL OF CHROMATOGRAPHY A, 2001, 910 (01) :87-93
[3]  
Brouwer E. R., 1994, J CHROMATOGR A, V678, P521
[4]   Gas chromatographic mass spectrometric identification and quantification of aniline after extraction from serum and derivatization with 4-carbethoxyhexafluorobutyryl chloride, a new derivative [J].
Dasgupta, A ;
Jagannath, C .
THERAPEUTIC DRUG MONITORING, 1999, 21 (02) :238-242
[5]   Gas chromatographic mass spectrometric identification and quantification of aniline after extraction from serum and derivatization with 2,2,2-trichloroethyl chloroformate, a novel derivative [J].
Dasgupta, A .
JOURNAL OF CHROMATOGRAPHY B, 1998, 716 (1-2) :354-358
[6]   On-line selective solid-phase extraction of 4-nitrophenol with β-cyclodextrin bonded silica [J].
Fan, Y ;
Feng, YQ ;
Da, SL .
ANALYTICA CHIMICA ACTA, 2003, 484 (02) :145-153
[7]   β-Cyclodextrin-bonded silica particles as the solid-phase extraction medium for the determination of phenol compounds in water samples followed by gas chromatography with flame ionization and mass spectrometry detection [J].
Faraji, H .
JOURNAL OF CHROMATOGRAPHY A, 2005, 1087 (1-2) :283-288
[8]   Preparation and characterization of an L-tyrosine-derivatized β-cyclodextrin-bonded silica stationary phase for liquid chromatography [J].
Feng, YQ ;
Xie, MJ ;
Da, SL .
ANALYTICA CHIMICA ACTA, 2000, 403 (1-2) :187-195
[9]   Derivatization of aromatic amines for analysis in ammunition wastewater .2. Derivatization of methyl anilines by iodination with a Sandmeyer-like reaction [J].
Haas, R ;
Schmidt, TC ;
Steinbach, K ;
vonLow, E .
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY, 1997, 359 (06) :497-501
[10]  
Hart AP, 1997, J FORENSIC SCI, V42, P693