1,2-HYDROGEN MIGRATION AND ALKENE FORMATION IN THE PHOTOEXCITED STATES OF ALKYLPHENYLDIAZOMETHANES

被引：63
作者：
CELEBI, S
LEYVA, S
MODARELLI, DA
PLATZ, MS
机构：
[1] OHIO STATE UNIV,DEPT CHEM,120 W 18TH AVE,COLUMBUS,OH 43210
[2] DOKUZ EYLUL UNIV,DEPT ENVIRONM ENGN,IZMIR,TURKEY
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1993年 / 115卷 / 19期
关键词：
D O I：
10.1021/ja00072a014
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Laser flash photolysis of alkylphenyldiazomethanes in the presence of pyridine produces easily detected ylides. The data indicate that photolysis of alkylphenyldiazomethanes leads to both carbene formation and direct formation of rearrangement products which do not derive from relaxed carbene intermediates.
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页码：8613 / 8620
页数：8
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