SIZE-DEPENDENT LATTICE CONTRACTION IN CDS1-XSEX NANOCRYSTALS EMBEDDED IN GLASS OBSERVED BY RAMAN-SCATTERING

被引:131
作者
SCAMARCIO, G [1 ]
LUGARA, M [1 ]
MANNO, D [1 ]
机构
[1] UNIV LECCE,DIPARTIMENTO SCI MAT,I-73100 LECCE,ITALY
来源
PHYSICAL REVIEW B | 1992年 / 45卷 / 23期
关键词
D O I
10.1103/PhysRevB.45.13792
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We demonstrate that CdS1-xSex nanocrystals embedded in glass suffer compressive strain which increases as the crystallite radius decreases. A model based on the dependence of the cluster surface free energy on the surface-to-volume ratio explains very well the observed blueshift of the phonon bands in the Raman spectra.
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收藏
页码:13792 / 13795
页数:4
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