OXIDATION OF ALKENES USING THE RUCL3/PHIO SYSTEM

被引：9
作者：
AGARWAL, DD
JAIN, R
CHAKRAVORTY, A
RASTOGI, R
机构：
[1] School of Studies in Chemistry, Jiwaji University, Gwalior
来源：
POLYHEDRON | 1992年 / 11卷 / 04期
关键词：
D O I：
10.1016/S0277-5387(00)83203-9
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The RuCl3 catalysed epoxidation of olefins gave more than 10% of epoxide. Pyridine addition increased the yield and selectivity of the epoxide. Epoxidation of norbornene gave exo- and endo-epoxide. The effect of surfactants supports the involvement of carbocation intermediates. The epoxidation of cyclic olefins follows the reactivity order cyclo-octene > norbornene > cyclopentene > cycloheptene > cyclohexene. Spectral studies suggest that oxo ruthenium(V) is the active oxidizing species.
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页码：463 / 467
页数：5
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