STEREOSELECTIVE SYNTHESIS OF CIS-DECALINS VIA DIELS-ALDER AND DOUBLE MICHAEL ADDITION OF SUBSTITUTED NAZAROV REAGENTS

被引：56

作者：

LAVALLEE, JF ^{[1
]}

SPINO, C ^{[1
]}

RUEL, R ^{[1
]}

HOGAN, KT ^{[1
]}

DESLONGCHAMPS, P ^{[1
]}

机构：

[1] UNIV SHERBROOKE,FAC SCI,DEPT CHIM,SYNTHESE ORGAN LAB,SHERBROOKE J1K 2R1,QUEBEC,CANADA

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1992年 / 70卷 / 05期

关键词：

D O I：

10.1139/v92-179

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The base-catalyzed cycloaddition and double Michael cyclization of substituted Nazarov reagents an of 1-phenylsulfinyl analogs, with 2-carbomethoxy-2-cyclohexen-1-one 1 yielding cis-decalins is reported. The reaction is highly stereoselective affording cis,cis- or cis,trans-decalins. Mechanistic aspects are briefly discussed.

引用

页码：1406 / 1426

页数：21

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