REVERSIBLE THERMAL-ISOMERIZATION OF 3 GEOMETRICAL-ISOMERS FOR CHLOROBIS(2-METHYL-8-QUINOLINOLATO)NITROSYLRUTHENIUM(III)

被引：7

作者：

IKEZAWA, H ^{[1
]}

MIKI, E ^{[1
]}

MIZUMACHI, K ^{[1
]}

ISHIMORI, T ^{[1
]}

WAKATSUKI, Y ^{[1
]}

机构：

[1] INST PHYS & CHEM RES, WAKO, SAITAMA 351, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 03期

关键词：

D O I：

10.1246/cl.1993.537

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reversible thermal isomerization among the trans and two kinds of cis geometrical isomers of [RuCl(2mqn)2(NO)] (2mqn=2-methyl-8-quinolinolate ion) was observed in degassed DMSO (dimethyl sulfoxide) at higher than 363 K. The mole ratio of the cis-1, the cis-2, and the trans isomers was 20:9:1 after the equilibrium was reached at 413 K, and it did not depend on the starting species.

引用

页码：537 / 540

页数：4

共 34 条

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[25] Electronic structure and molecular orbital study of the first excited state of the high-efficiency blue OLED material bis(2-methyl-8-quinolinolato)aluminum (III) hydroxide complex from ab initio and TD-B3LYP
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