REVERSIBLE THERMAL-ISOMERIZATION OF 3 GEOMETRICAL-ISOMERS FOR CHLOROBIS(2-METHYL-8-QUINOLINOLATO)NITROSYLRUTHENIUM(III)

被引：7

作者：

IKEZAWA, H ^{[1
]}

MIKI, E ^{[1
]}

MIZUMACHI, K ^{[1
]}

ISHIMORI, T ^{[1
]}

WAKATSUKI, Y ^{[1
]}

机构：

[1] INST PHYS & CHEM RES, WAKO, SAITAMA 351, JAPAN

来源：

CHEMISTRY LETTERS | 1993年 / 03期

关键词：

D O I：

10.1246/cl.1993.537

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reversible thermal isomerization among the trans and two kinds of cis geometrical isomers of [RuCl(2mqn)2(NO)] (2mqn=2-methyl-8-quinolinolate ion) was observed in degassed DMSO (dimethyl sulfoxide) at higher than 363 K. The mole ratio of the cis-1, the cis-2, and the trans isomers was 20:9:1 after the equilibrium was reached at 413 K, and it did not depend on the starting species.

引用

页码：537 / 540

页数：4

共 34 条

[1] CRYSTAL-STRUCTURES AND REVERSIBLE THERMAL-ISOMERIZATION OF 3 GEOMETRICAL-ISOMERS OF CHLOROBIS(2-ETHYL-8-QUINOLINOLATO)NITROSYLRUTHENIUM(II)
IKEZAWA, H
IKEZAWA, Y
MIKI, E
MIZUMACHI, K
ISHIMORI, T
INORGANICA CHIMICA ACTA, 1995, 238 (1-2) : 89 - 97
[2] CRYSTAL AND MOLECULAR-STRUCTURES OF 2 ISOMERS FOR CHLOROBIS-(2-METHYL-8-QUINOLINOLATO)NITROSYLRUTHENIUM(III)
KAMATA, Y
KIMURA, T
HIROTA, R
MIKI, E
MIZUMACHI, K
ISHIMORI, T
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1987, 60 (04) : 1343 - 1347
[3] CRYSTAL AND MOLECULAR STRUCTURE OF BIS(2-METHYL-8-QUINOLINOLATO)ALUMINUM(III)-MU-OXO-BIS(2-METHYL-8-QUINOLINOLATO)ALUMINUM(III)
KUSHI, Y
FERNANDO, Q
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1970, 92 (01) : 91 - &
[4] Tris(2-methyl-8-quinolinolato)iron(III) as a Novel Spectrophotometric Probe for Silanol Detection
NoBuo Uehara
Sumiko Kawata
Tokuo Shimizu
Analytical Sciences, 2006, 22 : 421 - 426
[5] Tris(2-methyl-8-quinolinolato)iron(III) as a novel spectrophotometric probe for silanol detection
Uehara, N
Kawata, S
Shimizu, T
ANALYTICAL SCIENCES, 2006, 22 (03) : 421 - 426
[6] Tris(2-methyl-8-quinolinolato)gallium(III) as a fluorescent probe for sensitive silanol-testing
Uehara, N
Kawata, S
Shimizu, T
ANALYTICAL SCIENCES, 2005, 21 (09) : 1099 - 1104
[7] Tris(2-methyl-8-quinolinolato)gallium(III) as a Fluorescent Probe for Sensitive Silanol-Testing
Nobuo Uehara
Sumiko Kawata
Tokuo Shimizu
Analytical Sciences, 2005, 21 : 1099 - 1104
[8] SYNTHESIS AND CHARACTERIZATION OF TECHNETIUM(V) 8-QUINOLINOLATES - X-RAY CRYSTAL-STRUCTURE OF CIS-CHLOROBIS(2-METHYL-8-QUINOLINOLATO)OXOTECHNETIUM(V)
WILCOX, BE
HEEG, MJ
DEUTSCH, E
INORGANIC CHEMISTRY, 1984, 23 (19) : 2962 - 2967
[9] COBALT(III) COMPLEXES WITH QUADRIDENTATE LIGANDS .4. THE PREPARATION AND PROPERTIES OF CIS-BETA-1 AND BETA-2 ISOMERS OF THE 2-METHYL-8-QUINOLINOLATO(TRIETHYLENETETRAMINE)-COBALT(III) AND RELATED COMPLEXES
YAMAMOTO, Y
TOYOTA, E
YAMAMOTO, Y
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1983, 56 (09) : 2721 - 2726
[10] LIGAND-SUBSTITUTION REACTION-KINETICS OF TRIS(8-QUINOLINOLATO)(8-QUINOLINOLATO)ALUMINUM(III) COMPLEXES AND BIS-(2-METHYL-8-QUINOLINOLATO)(8-QUINOLINOLATO)ALUMINUM(III) COMPLEXES WITH ETHYLENEDIAMINE-N,N,N',N'-TETRAACETIC ACID
HORIHATA, T
OKAMOTO, K
HIDAKA, J
EINAGA, H
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1988, 61 (08) : 2999 - 3001

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