FREQUENCY-DEPENDENCE OF VISCOELASTIC PROPERTIES OF SOME PHYSICAL GELS NEAR THE GEL POINT

被引：49

作者：

CUVELIER, G

LAUNAY, B

机构：

[1] ENSIA, Massy, 91300, 1, Av. des Olympiades

来源：

MAKROMOLEKULARE CHEMIE-MACROMOLECULAR SYMPOSIA | 1990年 / 40卷

关键词：

D O I：

10.1002/masy.19900400105

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The sol-gel and gel-sol transitions of three biopolymer gelling systems (gelatin, iota-carrageenan and xanthan-carob) have been studied by dynamic measurements. At the gel point a power law dependence of the storage (G') and loss (G") moduli on frequency is observed, with an exponent varying from 0.5 to 0.65. The variation of log(tg-delta = G"/G') versus the gelation (or melting) parameter (time or temperature) at different frequencies leads to a precise determination of the gel point.

引用

页码：23 / 31

页数：9

共 16 条

[1]

[Anonymous], 1979, SCALING CONCEPTS POL

[2]

AXELOS MAV, IN PRESS PHYS REV LE

[3] LINEAR VISCOELASTICITY AT THE GEL POINT OF A CROSS-LINKING PDMS WITH IMBALANCED STOICHIOMETRY [J].