PALLADIUM-CATALYZED ADDITION OF MASKED FORMYL CYANIDES ROCH(CN)(2) TO ALDEHYDES

被引：31

作者：

NEMOTO, H

KUBOTA, Y

YAMAMOTO, Y

机构：

[1] TOHOKU UNIV,FAC SCI,DEPT CHEM,SENDAI,MIYAGI 98077,JAPAN

[2] OKAZAKI INST MOLEC SCI,DEPT APPL MOLEC SCI,OKAZAKI,AICHI 444,JAPAN

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 14期

关键词：

D O I：

10.1039/c39940001665

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The palladium catalysed reactions of masked formyl cyanides 1 with aldehydes 2, followed by treatment with either diketene or acetic anhydride-pyridine, afford the addition products protected with acetylacetate 5 or acetyl group 6, respectively.

引用

页码：1665 / 1666

页数：2

共 9 条

[1] SYNTHESIS AND REACTIONS OF NICKEL AND PALLADIUM CARBON-BOUND ENOLATE COMPLEXES [J].

BURKHARDT, ER ;

BERGMAN, RG ;

HEATHCOCK, CH .

ORGANOMETALLICS, 1990, 9 (01) :30-44

[2] SILVER(I)-CATALYZED ASYMMETRIC ALDOL REACTION OF ISOCYANOACETATE [J].

HAYASHI, T ;

UOZUMI, Y ;

YAMAZAKI, A ;

SAWAMURA, M ;

HAMASHIMA, H ;

ITO, Y .

TETRAHEDRON LETTERS, 1991, 32 (24) :2799-2802

[3] SYNTHESIS OF NOVEL RHENIUM(I) ENOLATE COMPLEXES AS ACTIVE KEY INTERMEDIATES IN THE CATALYTIC ALDOL-TYPE REACTION [J].

HIRANO, M ;

ITO, Y ;

HIRAI, M ;

FUKUOKA, A ;

KOMIYA, S .

CHEMISTRY LETTERS, 1993, (12) :2057-2060

[4] SYNTHESIS OF 1,4-DICARBONYL COMPOUNDS VIA THE CONJUGATE ADDITION OF A MASKED ACTIVATED ESTER, ROCH(CN)2 [J].

KUBOTA, Y ;

NEMOTO, H ;

YAMAMOTO, Y .

JOURNAL OF ORGANIC CHEMISTRY, 1991, 56 (26) :7195-7196

[5] RUTHENIUM-CATALYZED ALDOL AND MICHAEL REACTIONS OF ACTIVATED NITRILES [J].

NAOTA, T ;

TAKI, H ;

MIZUNO, M ;

MURAHASHI, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (15) :5954-5955

[6] DEVELOPMENT OF A NEW ACYL ANION EQUIVALENT FOR THE PREPARATION OF MASKED ACTIVATED ESTERS AND THEIR USE TO PREPARE A DIPEPTIDE [J].

NEMOTO, H ;

KUBOTA, Y ;

YAMAMOTO, Y .

JOURNAL OF ORGANIC CHEMISTRY, 1990, 55 (15) :4515-4516

[7]

NEMOTO H, 1993, SYNLETT, P465

[8] ACYCLIC STEREOSELECTION .45. SYNTHESIS OF ETA-1 OXYGEN-BOUND RHODIUM ENOLATES - APPLICATIONS TO CATALYTIC ALDOL CHEMISTRY [J].

SLOUGH, GA ;

BERGMAN, RG ;

HEATHCOCK, CH .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (03) :938-949

[9] TRANSITION-METAL-CATALYZED ADDITION OF CERTAIN NUCLEOPHILES TO IMINES [J].

YAMAMOTO, Y ;

KUBOTA, Y ;

HONDA, Y ;

FUKUI, H ;

ASAO, N ;

NEMOTO, H .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (07) :3161-3162

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