CRYSTAL-STRUCTURE OF OSMYLATED C60 - CONFIRMATION OF THE SOCCER BALL FRAMEWORK

被引：595

作者：

HAWKINS, JM

MEYER, A

LEWIS, TA

LOREN, S

HOLLANDER, FJ

机构：

[1] Department of Chemistry, University of California, Berkeley

来源：

SCIENCE | 1991年 / 252卷 / 5003期

关键词：

D O I：

10.1126/science.252.5003.312

中图分类号：

O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];

学科分类号：

07 ; 0710 ; 09 ;

摘要：

An x-ray crystal structure that confirms the soccer ball-shaped carbon framework of C60 (buckminsterfullerene) is reported. An osmyl unit was added to C60 in order to break its pseudospherical symmetry and give an ordered crystal. The crystal structure of this derivative, C60(OsO4)(4-tert-butylpyridine)2, reveals atomic positions within the carbon cluster.

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页码：312 / 313

页数：2

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