REACTION OF KETENE IMINIUM IONS WITH DIFFERENT OLEFINS - NOVEL PREPARATION OF (+/-)-GRANDISOL, (+/-)-FRAGRANOL AND CORRESPONDING METHYL ETHERS

被引：10
作者：
GRANDGUILLOT, JC
ROUESSAC, F
机构：
来源：
TETRAHEDRON | 1991年 / 47卷 / 28期
关键词：
D O I：
10.1016/S0040-4020(01)87126-X
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
We describe here the preparation of grandisol, fragranol and several related cyclobutanic by-products by procedures employing a [2+2] cycloaddition reaction between an olefine and a ketene-iminium cation generated in situ from an alpha-chloroenamine. The regio- and stereospecificity of these cyclization reactions are studied.
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页码：5133 / 5148
页数：16
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