THE BORON-TRIFLUORIDE - BASE SYSTEM - APPLICATION OF THE COORDINATION MODEL OF REACTION-MECHANISMS

被引：8

作者：

OU, XB ^{[1
]}

WALLACE, R ^{[1
]}

JANZEN, AF ^{[1
]}

机构：

[1] UNIV MANITOBA,DEPT CHEM,WINNIPEG R3T 2N2,MANITOBA,CANADA

来源：

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE | 1993年 / 71卷 / 01期

关键词：

D O I：

10.1139/v93-008

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mechanism of reaction of boron trifluoride with amines, dialkyl ethers, and pyridine has been analyzed on the basis of the coordination model of reaction mechanisms. This model is tested mathematically by carrying out kinetic simulations of pathways P(X,C), accompanied by the calculation of structures of postulated intermediates by GAUSSIAN86 methods. Analyses of reaction mechanisms, including calculation of concentration vs. time cur-ves. are reported for the following systems: NH3-BF3, MeNH2-BF3, Me2O-Et2O-BF3, Me2O-Et2O:BF3, pyridine-BF3, pyridine-Me3N-BF3, F3B:N-N:BF3, and (N-N)BF2+.

引用

页码：51 / 59

页数：9

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