TEMPERATURE AND SITE DEPENDENCE OF THE RATE OF HYDROGEN AND DEUTERIUM ABSTRACTION BY METHYL RADICALS IN METHANOL GLASSES

被引：34

作者：

DOBA, T ^{[1
]}

INGOLD, KU ^{[1
]}

SIEBRAND, W ^{[1
]}

WILDMAN, TA ^{[1
]}

机构：

[1] NATL RES COUNCIL CANADA,DIV CHEM,OTTAWA K1A 0R6,ONTARIO,CANADA

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1984年 / 88卷 / 15期

关键词：

D O I：

10.1021/j150659a002

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

引用

页码：3165 / 3167

页数：3

共 19 条

[1] ABINITIO COMPUTATION OF FORCE CONSTANTS .3. SIMPLE PROCEDURE FOR EVALUATION OF X-H BOND-DISSOCIATION ENERGIES [J].

BERNARDI, F ;

SCHLEGEL, HB ;

WOLFE, S .

JOURNAL OF MOLECULAR STRUCTURE, 1976, 35 (01) :149-153

[2] THE SQUARE-ROOT-T LAW IN SOLID-PHASE REACTIONS VERIFICATION OF THE SQUARE-ROOT-T LAW STABILITY IN H-ATOM ABSTRACTION REACTIONS [J].

BOLSHAKOV, BV ;

STEPANOV, AA ;

TOLKATCHEV, VA .

INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1980, 12 (04) :271-281

[3] KINETIC PECULIARITY OF FREE VALENCE MIGRATION IN SOLID-STATE AS STUDIED THROUGH REACTION OF METHYL RADICALS WITH METHANOL AT 77K [J].

BOLSHAKOV, BV ;

TOLKATCHEV, VA .

CHEMICAL PHYSICS LETTERS, 1976, 40 (03) :468-470

[4] HYDROGEN-ATOM ABSTRACTION BY METHYL RADICALS IN METHANOL GLASSES AT 67-77 DEGREES K [J].

CAMPION, A ;

WILLIAMS, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (22) :7633-&

[5] EVALUATION OF REACTION-RATE CONSTANTS IN MEDIA WHERE THEY SHOW DISPERSION - HYDROGEN ABSTRACTION BY METHYL RADICALS IN A METHANOL GLASS [J].

DOBA, T ;

INGOLD, KU ;

SIEBRAND, W .

CHEMICAL PHYSICS LETTERS, 1984, 103 (05) :339-342

[6] RADICAL DECAY KINETICS IN ORGANIC GLASSES . SPATIAL EFFECTS AND ISOTOPE EFFECTS [J].

FRENCH, WG ;

WILLARD, JE .

JOURNAL OF PHYSICAL CHEMISTRY, 1968, 72 (13) :4604-&

[7]

Gray D.E., 1972, AM I PHYS HDB, V3rd, P4

[8] HYDROGEN-ATOM ABSTRACTION BY METHYL RADICALS IN METHANOL GLASSES AT 15-100 K - EVIDENCE FOR A LIMITING RATE CONSTANT BELOW 40 K BY QUANTUM-MECHANICAL TUNNELING [J].

HUDSON, RL ;

SHIOTANI, M ;

WILLIAMS, F .

CHEMICAL PHYSICS LETTERS, 1977, 48 (01) :193-196

[9] TUNNELING MODEL FOR HYDROGEN ABSTRACTION REACTIONS IN LOW-TEMPERATURE SOLIDS - APPLICATIONS TO REACTIONS IN ALCOHOL GLASSES AND ACETONITRILE CRYSTALS [J].

LEROY, RJ ;

MURAI, H ;

WILLIAMS, F .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1980, 102 (07) :2325-2334

[10] EFFECTS OF SOLUTES, DEUTERATION, AND ANNEALING ON PRODUCTION AND DECAY OF RADICALS IN GAMMA-IRRADIATED 3-METHYLPENTANE GLASSES [J].

NEISS, MA ;

WILLARD, JE .

JOURNAL OF PHYSICAL CHEMISTRY, 1975, 79 (08) :783-794

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