STRUCTURE-REACTIVITY RELATIONSHIPS - THE OXIDATION OF ALIPHATIC DIOLS ON A GOLD ELECTRODE

被引：13

作者：

LUCZAK, T ^{[1
]}

BELTOWSKABRZEZINSKA, M ^{[1
]}

HOLZE, R ^{[1
]}

机构：

[1] CARL VONOSSIETZKY UNIV,FACHBEREICH CHEM,D-26129 OLDENBURG,GERMANY

来源：

JOURNAL OF APPLIED ELECTROCHEMISTRY | 1993年 / 23卷 / 10期

关键词：

D O I：

10.1007/BF00266126

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electrooxidation of a series of vicinal and terminal aliphatic diols ranging from ethanediol to hexanediol including an unsaturated diol at a polycrystalline gold electrode in contact with an alkaline electrolyte solution has been studied. Significant differences found in the oxidation activity are rationalized based on the molecular structure and the different electrosorption behaviour as deduced from additional adsorption measurements.

引用

页码：1039 / 1044

页数：6

共 23 条

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