REACTIONS OF (VINYLIMINO)PHOSPHORANES AND RELATED-COMPOUNDS - ACCESS TO THE AZACARBOLINES AND APLYSINOPSINES

被引：48

作者：

CHAVIGNON, O

TEULADE, JC

ROCHE, D

MADESCLAIRE, M

BLACHE, Y

GUEIFFIER, A

CHABARD, JL

DAUPHIN, G

机构：

[1] UNIV MONTPELLIER 1,CNRS,URA 1111,F-34000 MONTPELLIER,FRANCE

[2] UNIV B PASCAL,CHIM ORGAN BIOL LAB,CNRS,URA 485,F-63170 CLERMONT FERRAND,FRANCE

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 21期

关键词：

D O I：

10.1021/jo00100a051

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Aza-Wittig-type reactions of iminophosphoranes 3a, 14a,b and 19, derived from azidovinyl (or -phenyl) derivatives and triphenylphosphine, with methyl or phenyl isocyanates were used to construct the framework of the azacarboline structures 7a,b-10, 20, 21a-d and aplysinopsine-type alkaloids 17a-d by electrocyclic ring closure or heterocumulene-mediated annelation.

引用

页码：6413 / 6418

页数：6

共 46 条

[1] ADDITION-REACTION OF PHENYL ISOCYANATE AND PHENYL ISOTHIOCYANATE TO PARTIALLY CYCLIC 1,3-DIAZA-1,3-BUTADIENES - SYNTHESIS OF ANNULATED 1,3,5-TRIAZINE-2,4(1H,3H)-DIONES AND 1,3,5-TRIAZINE-2,4(1H,3H)-DITHIONES [J].