GEL STRUCTURE AND WATER DIFFUSION PHENOMENA IN STARCH GELS STUDIED BY PULSED-FIELD GRADIENT STIMULATED ECHO NMR

被引:47
|
作者
OHTSUKA, A
WATANABE, T
SUZUKI, T
机构
[1] Department of Food Science and Technology, Tokyo University of Fisheries, Minato-ku, Tokyo, 108, 4-5-7, Konan
关键词
D O I
10.1016/0144-8617(94)90144-9
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Water diffusion phenomena in potato starch gels (starch concentrations in the range of 17.1-42.0 w/w%) were observed as restricted diffusion by the pulsed field gradient stimulated echo (PFGSTE) NMR method. The size of water compartments, a, permeability of the barriers, p, and self diffusion coefficient of compartmentalized water between the barriers, D-0, were estimated using a theoretical equation. These parameters changed with both starch concentration and duration of storage time. The structure of the starch gels and the structural change during retrogradation are discussed with respect to these parameters.
引用
收藏
页码:95 / 100
页数:6
相关论文
共 50 条
  • [1] The effect of sugars on the diffusion of water in starch gels: a pulsed field gradient NMR study
    Farhat, IA
    Loisel, E
    Saez, P
    Derbyshire, W
    Blanshard, JMV
    INTERNATIONAL JOURNAL OF FOOD SCIENCE AND TECHNOLOGY, 1997, 32 (05): : 377 - 387
  • [2] Diffusion processes in polymer gels as studied by pulsed field-gradient spin-echo NMR spectroscopy
    Matsukawa, S
    Yasunaga, H
    Zhao, C
    Kuroki, S
    Kurosu, H
    Ando, I
    PROGRESS IN POLYMER SCIENCE, 1999, 24 (07) : 995 - 1044
  • [3] Diffusion processes in polymer gels as studied by pulsed field-gradient spin-echo NMR spectroscopy
    Matsukawa, S.
    Yasunaga, H.
    Zhao, C.
    Kuroki, S.
    Kurosu, H.
    Ando, I.
    Progress in Polymer Science (Oxford), 1999, 24 (07): : 995 - 1044
  • [4] Diffusion of polyethyleneglycols in casein solutions and gels as studied by pulsed field gradient NMR
    Colsenet, R
    Soderman, O
    Mariette, F
    MAGNETIC RESONANCE IMAGING, 2005, 23 (02) : 347 - 348
  • [5] Diffusion measurements of water, ubiquinone and lipid bilayer inside a cylindrical nanoporous support: A stimulated echo pulsed-field gradient MAS-NMR investigation
    Wattraint, O
    Sarazin, C
    BIOCHIMICA ET BIOPHYSICA ACTA-BIOMEMBRANES, 2005, 1713 (01): : 65 - 72
  • [6] The self-diffusion behavior of polyethylene glycol in cartilage as studied by pulsed-field gradient NMR
    Mohamed, EETEA
    Gröger, S
    Schiller, J
    Stallmach, F
    Kärger, J
    Arnold, K
    PHYSICA MEDICA-EUROPEAN JOURNAL OF MEDICAL PHYSICS, 2005, 21 (02): : 69 - 73
  • [7] PULSED-FIELD GRADIENT SPIN-ECHO NMR MEASUREMENT OF WATER DIFFUSION-COEFFICIENT IN THICKENING AND GELLING AGENTS - GUAR GALACTOMANNAN SOLUTIONS AND PECTIN GELS
    BROSIO, E
    DUBALDO, A
    VERZEGNASSI, B
    CELLULAR AND MOLECULAR BIOLOGY, 1994, 40 (04) : 569 - 573
  • [8] Studies of asphaltenes by the use of pulsed-field gradient spin echo NMR
    Östlund, JA
    Andersson, SI
    Nydén, M
    FUEL, 2001, 80 (11) : 1529 - 1533
  • [9] Diffusion of n-hexane in 5A zeolite studied by the neutron spin-echo and pulsed-field gradient NMR techniques
    Jobic, H
    Paoli, H
    Méthivier, A
    Ehlers, G
    Kärger, J
    Krause, C
    MICROPOROUS AND MESOPOROUS MATERIALS, 2003, 59 (2-3) : 113 - 121
  • [10] Lithium diffusion in lithium nitride by pulsed-field gradient NMR
    Wang, Zhongli
    Gobet, Mallory
    Sarou-Kanian, Vincent
    Massiot, Dominique
    Bessada, Catherine
    Deschamps, Michael
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2012, 14 (39) : 13535 - 13538