METAL ALKOXIDE PRIMERS IN THE ADHESIVE BONDING OF MILD-STEEL

被引:0
作者
MENON, B [1 ]
PIKE, RA [1 ]
WIGHTMAN, JP [1 ]
机构
[1] VIRGINIA POLYTECH INST & STATE UNIV,CTR ADHES & SELANT SCI,DEPT CHEM,BLACKSBURG,VA 24061
关键词
ALUMINUM ALKOXIDE; TITANIUM ALKOXIDE; SILICON ALKOXIDE; PRIMERS; DURABILITY; STEEL; RELATIVE HUMIDITY; ADHESION;
D O I
10.1163/156856191X00279
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The effects of metal alkoxide type and relative humidity on the durability of alkoxide-primed, adhesively bonded steel wedge crack specimens have been determined. Aluminum tri-sec-butoxide, aluminum tri-tert-butoxide, tetrabutyl orthosilicate, and titanium(IV) butoxide were used as alkoxide primers. Grit-blasted, acetone-rinsed mild steel adherends were the substrates bonded with epoxy and polyethersulfone. The two aluminum alkoxides significantly enhanced the durability of the adhesively bonded steel, while the titanium alkoxide showed no improvement in durability over a nonprimed control. The silicon alkoxide-primed samples gave an intermediate response. The failure plane in the adhesively bonded samples varied with the relative humidity during the priming process.
引用
收藏
页码:883 / 893
页数:11
相关论文
共 14 条
[1]  
Altenpohl DG, 1962, CORROSION, V18, P143
[2]  
Bradley D. C., 1978, METAL ALKOXIDES
[3]   METAL ALKOXIDE PRIMERS IN TITANIUM EPOXY BONDING [J].
FILBEY, JA ;
WIGHTMAN, JP .
JOURNAL OF ADHESION, 1989, 28 (01) :23-39
[4]  
HARDWICK DA, 1984, J MATER SCI, V19, P223, DOI 10.1007/BF02403129
[5]   INORGANIC ADHESIVE PRIMERS - EFFECT OF METAL-SURFACE TREATMENTS [J].
PIKE, RA ;
LAMM, FP .
JOURNAL OF ADHESION, 1988, 26 (2-3) :171-179
[6]  
PIKE RA, 1985, INT J ADHES ADHES, V5, P3
[7]  
PIKE RA, 1985, 17TH P NAT SAMPE TEC, P448
[8]  
PIKE RA, 1986, INT J ADHES ADHES, V6, P21
[9]  
PIKE RA, 1988, ADHESIVES SEALANTS C, P141
[10]  
PIKE RA, 1986, Patent No. 4623591