CORROSION STUDY OF TITANIUM ANODES WITH A COATING OF MIXED RUTHENIUM AND TITANIUM-OXIDE

被引：0
作者：
MILLET, JMM
SEBAOUN, A
BERTUCCI, M
机构：
[1] UNIV TOULON & VAR,EQUIPE MAT FINAL SPECIF,PHYSICOCHIM MAT & MILIEU MARIN LAB,F-83957 LA GARDE,FRANCE
[2] ATOCHEM,CTR RECH RHONE ALPES,F-69310 PIERRE BENITE,FRANCE
来源：
ANNALES DE CHIMIE-SCIENCE DES MATERIAUX | 1993年 / 18卷 / 04期
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中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The degradation of titanium anodes coated with mixed ruthenium and titanium oxide, in strongly acidified medium (1M H2SO4) has been followed using scanning electron microscopy. The corrosion mechanism appears to be based upon the propagation of cracks initialy present in the electrode coating which progress from the surface of the coating to the titanium substrate. The propagation of the cracks is caused by the dissolution of the oxide coating at the bottom of the cracks where increased acidification of the solution, due to the electrolysis, takes place.
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页码：199 / 210
页数：12
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